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http://hdl.handle.net/2445/102067
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DC Field | Value | Language |
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dc.contributor.author | Salomó i Prat, Ernest | - |
dc.contributor.author | Orgué Gassol, Sílvia | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.date.accessioned | 2016-09-22T10:03:10Z | - |
dc.date.available | 2017-03-22T23:01:24Z | - |
dc.date.issued | 2016-03-22 | - |
dc.identifier.issn | 0039-7881 | - |
dc.identifier.uri | http://hdl.handle.net/2445/102067 | - |
dc.description.abstract | A novel one-pot reductive methodol. for the synthesis of optically pure tert-butylmethylphosphine-borane is reported. The prepn. uses as the starting material tert-butylmethylphosphinous acid-borane, which is available in both enantiomeric forms from cis-1,2-aminoindanol and tert-butyldichlorophosphine. The process is based on the redn. of a mixed anhydride, the configurational stability of which has been studied in several solvents and temps. Tetrabutylammonium borohydride was the best reducing agent allowing for the development of a practical process. To demonstrate the utility of the new methodol., the product obtained in this manner was used in the prepn. of Quinox-P*. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Georg Thieme Verlag | - |
dc.relation.isformatof | Versió postprint del document publicat a: http://dx.doi.org/10.1055/s-0035-1561854 | - |
dc.relation.ispartof | Synthesis. Journal of Synthetic Organic Chemistry, 2016, vol. 48, num. 16, p. 2659-2663 | - |
dc.relation.uri | http://dx.doi.org/10.1055/s-0035-1561854 | - |
dc.rights | (c) Georg Thieme Verlag, 2016 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Compostos fosforosos | - |
dc.subject.classification | Lligands (Bioquímica) | - |
dc.subject.other | Phosphorus compounds | - |
dc.subject.other | Ligands (Biochemistry) | - |
dc.title | Efficient preparation of (S)- and (R)-tert-Butylmethylphosphine-Borane: a novel entry to important P-Stereogenic ligands | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 663020 | - |
dc.date.updated | 2016-09-22T10:03:15Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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663020.pdf | 387.8 kB | Adobe PDF | View/Open |
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