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http://hdl.handle.net/2445/106627
Title: | 'Aggregation induced emission' active iridium(III) complexes with applications in mitochondrial staining |
Author: | Alam, Parvej Dash, Subhra Climent Biescas, Claudia Kaur, Gurpreet Choudhury, Angshuman Roy Casanova i Casas, David Alemany i Cahner, Pere Chowdhury, Rajdeep Laskar, Inamur Rahaman |
Keywords: | Mitocondris Citotoxicitat per mediació cel·lular Síntesi orgànica Mitochondria Cell-mediated cytotoxicity Organic synthesis |
Issue Date: | 17-Jan-2017 |
Publisher: | Royal Society of Chemistry |
Abstract: | Two new bis-cyclometalated iridium(III) complexes, [Ir(F2ppy)2(L)] and [Ir(ppy)2(L)], where F2ppy 1⁄4 2-(20,40- difluoro)phenylpyridine, ppy 1⁄4 2-phenylpyridine and L 1⁄4 1,2-((pyridin-2-ylimino)methyl)phenol, have been designed and synthesized by a convenient route. We have univocally characterized their structure by 1H NMR, 19F NMR, HRMS and SXRD. Both complexes exhibit strong 'Aggregation Induced Emission (AIE)' activity, which has been investigated using spectroscopy measurements, ab initio quantum chemical calculations and by analysing their crystal packing. One of the complexes has been shown to have a potential application as a non-toxic bio-imaging probe for mitochondrial staining. |
Note: | Reproducció del document publicat a: https://doi.org/10.1039/c6ra24792j |
It is part of: | RSC Advances, 2017, vol. 7, p. 5642-5648 |
URI: | http://hdl.handle.net/2445/106627 |
Related resource: | https://doi.org/10.1039/c6ra24792j |
ISSN: | 2046-2069 |
Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
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