Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/107929
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dc.contributor.authorMancinelli, Andrea-
dc.contributor.authorAlamillo, Carla-
dc.contributor.authorAlbert Mach, Joan-
dc.contributor.authorAriza Piquer, Xavier-
dc.contributor.authorEtxabe, Haizea-
dc.contributor.authorFarràs i Soler, Jaume-
dc.contributor.authorGarcía Gómez, Jordi-
dc.contributor.authorGranell Sanvicente, Jaime Ramón-
dc.contributor.authorQuijada, F. Javier-
dc.date.accessioned2017-03-06T12:12:39Z-
dc.date.available2017-03-06T12:12:39Z-
dc.date.issued2017-02-15-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/2445/107929-
dc.description.abstract3,3-Disubstituted tetrahydroisoquinolines are prepared in one step from Michael acceptors and 2-phenylethylamines under Pd catalysis and Ag2CO3 as an oxidant. Presumably, activation of an ortho C-H bond of the aromatic ring with Pd(II) is directed by the primary amine to form a palladacycle. Insertion of the olefin, subsequent conjugated addition of the amine, and reductive elimination of Pd(0) affords the expected products. Silver carbonate is not necessary when 2-phenylethylamines are converted previously to N-benzoyloxy-2-phenylethylamines.-
dc.format.extent9 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofReproducció del document publicat a: http://pubs.acs.org/doi/abs/10.1021/acs.organomet.6b00944; http://10.1021/acs.organomet.6b00944-
dc.relation.ispartofOrganometallics, 2017, vol. 36, num. 4, p. 911-919-
dc.rightscc-by-nc (c) American Chemical Society , 2017-
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/es-
dc.subject.classificationCompostos heterocíclics-
dc.subject.classificationPal·ladi (Element químic)-
dc.subject.classificationCatàlisi-
dc.subject.otherHeterocyclic compounds-
dc.subject.otherPalladium-
dc.subject.otherCatalysis-
dc.titlePreparation of substituted tetrahydroisoquinolines by Pd(II)-catalyzed NH2-directed insertion of Michael acceptors into C-H bonds followed by NH2-conjugated additions-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec668746-
dc.date.updated2017-03-06T12:12:39Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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