Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/108384
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dc.contributor.authorOrgué Gassol, Sílvia-
dc.contributor.authorLeon, Thierry-
dc.contributor.authorRiera i Escalé, Antoni-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.date.accessioned2017-03-14T08:29:48Z-
dc.date.available2017-03-14T08:29:48Z-
dc.date.issued2014-12-29-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/2445/108384-
dc.description.abstractThe asymmetric intermolecular and catalytic Pauson-Khand reaction has remained an elusive goal since Khand and Pauson discovered this transformation. Using a novel family of P-stereogenic phosphanes, we developed the first catalytic system with useful levels of enantioselection for the reaction of norbornadiene and trimethylsilylacetylene. The results demonstrate that Co-bisphosphane systems are sufficiently reactive and that they lead to high selectivity in the intermolecular process.-
dc.format.extent5 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/ol503329g-
dc.relation.ispartofOrganic Letters, 2014, vol. 17, p. 250-253-
dc.relation.urihttps://doi.org/10.1021/ol503329g-
dc.rights(c) American Chemical Society , 2014-
dc.subject.classificationReacció de Pauson-Khand-
dc.subject.classificationCatàlisi asimètrica-
dc.subject.otherPauson-Khand reaction-
dc.subject.otherEnantioselective catalysis-
dc.titleAsymmetric intermolecular cobalt-catalyzed Pauson-Khand reaction using a p-stereogenic bis-phosphaneeng
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec646125-
dc.date.updated2017-03-14T08:29:48Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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