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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/114291
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dc.contributor.authorSalomó i Prat, Ernest-
dc.contributor.authorPrades, Amparo-
dc.contributor.authorRiera i Escalé, Antoni-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.date.accessioned2017-07-25T08:38:28Z-
dc.date.available2018-06-22T22:01:24Z-
dc.date.issued2017-06-22-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/2445/114291-
dc.description.abstractThe preparation of shelf-stable crystalline salts of tert-butylmethylphosphinous acid borane 1 is described. X-ray analysis of diisopropylammonium tert-butylmethylphosphinite borane 4 revealed the existence of a cyclic hydrogen-bond network in the solid state which accounts for the increased melting point and stability. Dialkylammonium phosphinite boranes are convenient precursors of the chiral tert-butylmethylphosphine fragment. Compound 4 can be directly employed in SN2@P reactions with different nucleophiles to yield valuable P-stereogenic intermediates and ligands.-
dc.format.extent5 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.joc.7b01180-
dc.relation.ispartofJournal of Organic Chemistry, 2017-
dc.relation.urihttps://doi.org/10.1021/acs.joc.7b01180-
dc.rights(c) American Chemical Society, 2017-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationLligands (Bioquímica)-
dc.subject.classificationCompostos fosforosos-
dc.subject.classificationCatàlisi asimètrica-
dc.subject.otherLigands (Biochemistry)-
dc.subject.otherPhosphorus compounds-
dc.subject.otherEnantioselective catalysis-
dc.titleDialkylammonium tert-Butylmethylphosphinites: Stable Intermediates for the Synthesis of P-Stereogenic Ligands-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.date.updated2017-07-25T08:38:28Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid28640640-
Appears in Collections:Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))
Articles publicats en revistes (Química Inorgànica i Orgànica)

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