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http://hdl.handle.net/2445/118465
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DC Field | Value | Language |
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dc.contributor.author | Camps García, Pelayo | - |
dc.contributor.author | Gómez Nadal, Tània | - |
dc.contributor.author | Otermin Esteras, Ane | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2017-12-04T15:23:15Z | - |
dc.date.available | 2017-12-04T15:23:15Z | - |
dc.date.issued | 2017-05-31 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2445/118465 | - |
dc.description.abstract | 7a-(Methoxycarbonyl)-N-methyl-1,3a,5,6,7,7a-hexahydro-4H-1,4,6-(epiethane[1,1,2]triyl) indene-4,9-dicarboximide has been prepared through a modification of a previous synthetic sequence, in which the benzyloxymethyl hydroxyl protecting group has been replaced by methoxymethyl, to avoid the apparent formation of a benzyl ester derivative as a side product. The overall yield of the new synthetic sequence is comparable to the previous one. Two advantages of the new procedure are: (a) no benzyl ester was formed and (b) a stereoisomeric mixture of syn- and anti-alcohols at the beginning of the synthetic sequence could be separated and the rest of the synthesis could be carried out with the main syn-stereoisomer instead of the corresponding stereoisomeric mixture as it was the case in the previous process. | - |
dc.format.extent | 15 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/molecules22060906 | - |
dc.relation.ispartof | Molecules, 2017, vol. 22, num. 6, p. 906 | - |
dc.relation.uri | https://doi.org/10.3390/molecules22060906 | - |
dc.rights | cc-by (c) Camps García, Pelayo et al., 2017 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Síntesi orgànica | - |
dc.subject.classification | Compostos policíclics | - |
dc.subject.classification | Difracció de raigs X | - |
dc.subject.other | Organic synthesis | - |
dc.subject.other | Polycyclic compounds | - |
dc.subject.other | X-rays diffraction | - |
dc.title | Alternative access to functionalized 2,8-ethanonoradamantane derivatives | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 671825 | - |
dc.date.updated | 2017-12-04T15:23:15Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 28561800 | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) Articles publicats en revistes (Institut de Biomedicina (IBUB)) |
Files in This Item:
File | Description | Size | Format | |
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671825.pdf | 1.2 MB | Adobe PDF | View/Open |
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