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http://hdl.handle.net/2445/119967Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Valero González, Guillem | - |
| dc.contributor.author | León, Carlos M. | - |
| dc.contributor.author | Moyano i Baldoire, Albert | - |
| dc.date.accessioned | 2018-02-19T11:19:17Z | - |
| dc.date.available | 2018-02-19T11:19:17Z | - |
| dc.date.issued | 2015-06-12 | - |
| dc.identifier.issn | 2300-4630 | - |
| dc.identifier.uri | http://hdl.handle.net/2445/119967 | - |
| dc.description.abstract | Solvent effects in the L-tryptophan-catalyzed Mannich reaction between hydroxyacetone and glyoxylate imines have been examined. The use of a DMSO/1-butanol (4:1 v/v) mixture as solvent at rt provided the expected Mannich adducts in good yields, high anti-diastereoselectivity (up to 10.3:1 anti/syn ratio) and excellent enantioselectivities (up to >99.9% ee for the anti isomer) | - |
| dc.format.extent | 10 p. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | De Gruyter Open | - |
| dc.relation.isformatof | https://doi.org/10.1515/asorg-2015-0001 | - |
| dc.relation.ispartof | Asymmetric Catalysis, 2015, vol. 2, num. 1, p. 7-16 | - |
| dc.relation.uri | https://doi.org/10.1515/asorg-2015-0001 | - |
| dc.rights | cc by-nc-nd (c) Valero González, Guillem et al., 2015 | - |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | - |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
| dc.subject.classification | Aminoàcids | - |
| dc.subject.classification | Catàlisi asimètrica | - |
| dc.subject.other | Amino acids | - |
| dc.subject.other | Enantioselective catalysis | - |
| dc.title | Solvent-controlled diastereoselectivity in tryptophan-catalyzed Mannich reactions | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.identifier.idgrec | 668850 | - |
| dc.date.updated | 2018-02-19T11:19:17Z | - |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 668850.pdf | 525.43 kB | Adobe PDF | View/Open |
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