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Title: A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
Author: Gholizadeh Dogaheh, Samira
Khanmohammadi, Hamid
Sañudo Zotes, Eva Carolina
Keywords: Propietats magnètiques
Lligands (Bioquímica)
Magnetic properties
Ligands (Biochemistry)
Issue Date: 5-Sep-2017
Publisher: Elsevier Ltd
Abstract: In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu-3(HYDRAV)(2)CI2] (HYDRAV-Cu). The ligand HYDRAVH(2) and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH(2) contains a fluorescent naphthyl group and emission properties of both HYDRAVH(2) and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu. (C) 2017 Elsevier Ltd. All rights reserved.
Note: Versió postprint del document publicat a:
It is part of: Polyhedron, 2017, vol. 133, p. 48-53
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ISSN: 0277-5387
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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