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Title: Co(II) and Cu(II) fluorescent complexes with acridine based ligands
Author: Gholizadeh Dogaheh, Samira
Heras Ojea, M. J.
Rosado Piquer, Lidia
Artús i Surroca, Lluís
Khanmohammadi, Hamid
Aromí Bedmar, Guillem
Sañudo Zotes, Eva Carolina
Keywords: Lligands (Bioquímica)
Ligands (Biochemistry)
Issue Date: 2016
Publisher: Wiley-VCH
Abstract: The condensation reaction of salicylaldehyde or 2‐hydroxynaphthaldehyde with a diamino organic group (Acridine Yellow or diaminoacridine) resulted in the Schiff‐base ligands ACRI‐1, ACRI‐2 and ACRI‐3, with the last two hitherto unknown. Fluorescent ACRI‐1, ACRI‐2 and ACRI‐3 were designed to provide iminophenolic binding pockets for two transition metals and ferromagnetic exchange between the metals. Following our report on the complex [Co2(ACRI‐1)2] (1Co), we report herein the reactions of ACRI‐1, ACRI‐2 and ACRI‐3 with CoII and CuII salts, which afforded the new fluorescent complexes [Cu2(ACRI‐1)2] (1Cu), [Co2(ACRI‐2)2] (2Co), [Cu2(ACRI‐2)2] (2Cu), [Co2(ACRI‐3)2(H2O)4] (3Co) and [Cu2(ACRI‐3)2] (3Cu)
Note: Versió postprint del document publicat a:
It is part of: European Journal of Inorganic Chemistry, 2016, p. 3314-3321
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ISSN: 1434-1948
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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