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Title: From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design
Author: Casellas, Nicolas M.
Pujals Riatós, Silvia
Bochicchio, Davide
Pavan, Giovanni M.
Torres, Tomás
Albertazzi, Lorenzo
García Iglesias, Miguel
Keywords: Polimerització
Estructura molecular
Molecular structure
Issue Date: 27-Mar-2018
Abstract: Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).
Note: Versió postprint del document publicat a:
It is part of: Chemical Communications, 2018, vol. 54, num. 33, p. 4112-4115
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Appears in Collections:Articles publicats en revistes (Institut de Bioenginyeria de Catalunya (IBEC))

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