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http://hdl.handle.net/2445/127393| Title: | From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design |
| Author: | Casellas, Nicolas M. Pujals Riatós, Silvia Bochicchio, Davide Pavan, Giovanni M. Torres, Tomás Albertazzi, Lorenzo García Iglesias, Miguel |
| Keywords: | Polimerització Estructura molecular Aigua Polymerization Molecular structure Water |
| Issue Date: | 27-Mar-2018 |
| Abstract: | Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values). |
| Note: | Versió postprint del document publicat a: http://dx.doi.org/10.1039/C8CC01259H |
| It is part of: | Chemical Communications, 2018, vol. 54, num. 33, p. 4112-4115 |
| URI: | http://hdl.handle.net/2445/127393 |
| Related resource: | https://doi.org/10.1039/C8CC01259H |
| Appears in Collections: | Articles publicats en revistes (Institut de Bioenginyeria de Catalunya (IBEC)) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| L22_2018_Chemical Communications_54_4112_OA.pdf | 1.49 MB | Adobe PDF | View/Open |
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