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http://hdl.handle.net/2445/127958| Title: | General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary |
| Author: | Kennington, Stuart C. D. Gómez Palomino, Alejandro Salomó i Prat, Ernest Romea, Pedro Urpí Tubella, Fèlix Font Bardia, Ma. Mercedes |
| Keywords: | Titani Estereoquímica Titanium Stereochemistry |
| Issue Date: | 14-Jun-2018 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | A comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c8ob01074a |
| It is part of: | Organic & Biomolecular Chemistry, 2018, vol. 16, p. 4807-4815 |
| URI: | http://hdl.handle.net/2445/127958 |
| Related resource: | https://doi.org/10.1039/c8ob01074a |
| ISSN: | 1477-0520 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 681138.pdf | 1.57 MB | Adobe PDF | View/Open |
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