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Title: General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary
Author: Kennington, Stuart C. D.
Gómez Palomino, Alejandro
Salomo, Ernest
Romea, Pedro
Urpí Tubella, Fèlix
Font Bardia, Ma. Mercedes
Keywords: Titani
Issue Date: 14-Jun-2018
Publisher: Royal Society of Chemistry
Abstract: A comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation
Note: Versió postprint del document publicat a:
It is part of: Organic & Biomolecular Chemistry, 2018, vol. 16, p. 4807-4815
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ISSN: 1477-0520
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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