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http://hdl.handle.net/2445/128156
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DC Field | Value | Language |
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dc.contributor.author | Gómez Palomino, Alejandro | - |
dc.contributor.author | Romea, Pedro | - |
dc.contributor.author | Urpí Tubella, Fèlix | - |
dc.date.accessioned | 2019-02-12T10:48:08Z | - |
dc.date.available | 2019-07-01T05:10:16Z | - |
dc.date.issued | 2018-07-01 | - |
dc.identifier.issn | 0039-7881 | - |
dc.identifier.uri | http://hdl.handle.net/2445/128156 | - |
dc.description.abstract | A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates. | - |
dc.format.extent | 6 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Georg Thieme Verlag | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966 | - |
dc.relation.ispartof | Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726 | - |
dc.relation.uri | https://doi.org/10.1055/s-0037-1609966 | - |
dc.rights | (c) Georg Thieme Verlag, 2018 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Titani | - |
dc.subject.classification | Estereoquímica | - |
dc.subject.classification | Quiralitat | - |
dc.subject.other | Titanium | - |
dc.subject.other | Stereochemistry | - |
dc.subject.other | Chirality | - |
dc.title | Stereoselective oxidation of titanium(IV) enolates with oxygen | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 681108 | - |
dc.date.updated | 2019-02-12T10:48:08Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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681108.pdf | 437.41 kB | Adobe PDF | View/Open |
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