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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/128198
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dc.contributor.authorCoussanes, Guilhem-
dc.contributor.authorJakobi, Harald-
dc.contributor.authorLindell, Stephen-
dc.contributor.authorBonjoch i Sesé, Josep-
dc.date.accessioned2019-02-13T11:17:03Z-
dc.date.available2019-05-16T05:10:17Z-
dc.date.issued2018-05-16-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/2445/128198-
dc.description.abstractA cyanoborohydride-promoted radical cyclization methodology has been developed to access α-chlorolactams in a simple and efficient way, using NaBH3CN and trichloroacetamides easily available from allylic and homoallylic secondary amines. This methodology allowed the synthesis of a library of αchlorolactams (mono and bicyclic), which were tested for herbicidal activity, trans-3-chloro-4-methyl-1-(3-trifluoromethyl)phenyl-2-pyrrolidinone being the most active.-
dc.format.extent6 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherWiley-VCH-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/chem.201800210-
dc.relation.ispartofChemistry-A European Journal, 2018, vol. 24, num. 32, p. 8151-8156-
dc.relation.urihttps://doi.org/10.1002/chem.201800210-
dc.rights(c) Wiley-VCH, 2018-
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)-
dc.subject.classificationLactames-
dc.subject.classificationHerbicides-
dc.subject.classificationRadicals (Química)-
dc.subject.classificationSíntesi orgànica-
dc.subject.otherLactams-
dc.subject.otherHerbicides-
dc.subject.otherRadicals (Chemistry)-
dc.subject.otherOrganic synthesis-
dc.titleSynthesis of a-chlorolactams by cyanoborohydride-mediated radical cyclization of trichloroacetamides-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec683223-
dc.date.updated2019-02-13T11:17:03Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid29603478-
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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