Please use this identifier to cite or link to this item:
Title: A novel family of triangular CoII2LnIII and CoII2YIII clusters by the employment of Di-2-Pyridyl ketone
Author: Efthymiou, Constantinos G.
Fhuaráin, Áine Ní
Mayans Ayats, Júlia
Tasiopoulos, Anastasios
Perlepes, Spyros P.
Papatriantafyllopoulou, Constantina
Keywords: Cobalt
Clústers metàl·lics
Metalls de terres rares
Metal clusters
Rare earth metals
Issue Date: 4-Jun-2019
Publisher: MDPI
Abstract: The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triangular clusters, [CoII2MIII{(py)2C(OEt)(O)}4(NO3)(H2O)]2[M(NO3)5](ClO4)2 (M = Gd, 1; Dy, 2; Tb, 3; Y, 4), where (py)2C(OEt)(O)− is the monoanion of the hemiketal form of (py)2CO. Clusters 1-4 are the first reported Co/4f (1-3) and Co/Y (4) species bearing (py)2CO or its derivatives, despite the fact that over 200 metal clusters bearing this ligand have been reported so far. Variable-temperature, solid-state dc and ac magnetic susceptibility studies were carried out on 1-4 and revealed the presence of weak ferromagnetic exchange interactions between the metal ions (JCo-Co = +1.3 and +0.40 cm−1 in 1 and 4, respectively; JCo-Gd = +0.09 cm−1 in 1). The ac susceptibility studies on 2 revealed nonzero, weak out-of-phase (χ''M) signals below ~5 K.
Note: Reproducció del document publicat a:
It is part of: Magnetochemistry, 2019, vol. 5, num. 2
Related resource:
ISSN: 2312-7481
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

Files in This Item:
File Description SizeFormat 
690646.pdf1.22 MBAdobe PDFView/Open

This item is licensed under a Creative Commons License Creative Commons