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DC Field | Value | Language |
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dc.contributor.author | Efthymiou, Constantinos G. | - |
dc.contributor.author | Fhuaráin, Áine Ní | - |
dc.contributor.author | Mayans Ayats, Júlia | - |
dc.contributor.author | Tasiopoulos, Anastasios | - |
dc.contributor.author | Perlepes, Spyros P. | - |
dc.contributor.author | Papatriantafyllopoulou, Constantina | - |
dc.date.accessioned | 2019-07-16T07:55:54Z | - |
dc.date.available | 2019-07-16T07:55:54Z | - |
dc.date.issued | 2019-06-04 | - |
dc.identifier.issn | 2312-7481 | - |
dc.identifier.uri | http://hdl.handle.net/2445/137298 | - |
dc.description.abstract | The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triangular clusters, [CoII2MIII{(py)2C(OEt)(O)}4(NO3)(H2O)]2[M(NO3)5](ClO4)2 (M = Gd, 1; Dy, 2; Tb, 3; Y, 4), where (py)2C(OEt)(O)− is the monoanion of the hemiketal form of (py)2CO. Clusters 1-4 are the first reported Co/4f (1-3) and Co/Y (4) species bearing (py)2CO or its derivatives, despite the fact that over 200 metal clusters bearing this ligand have been reported so far. Variable-temperature, solid-state dc and ac magnetic susceptibility studies were carried out on 1-4 and revealed the presence of weak ferromagnetic exchange interactions between the metal ions (JCo-Co = +1.3 and +0.40 cm−1 in 1 and 4, respectively; JCo-Gd = +0.09 cm−1 in 1). The ac susceptibility studies on 2 revealed nonzero, weak out-of-phase (χ''M) signals below ~5 K. | - |
dc.format.extent | 12 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/magnetochemistry5020035 | - |
dc.relation.ispartof | Magnetochemistry, 2019, vol. 5, num. 2 | - |
dc.relation.uri | https://doi.org/10.3390/magnetochemistry5020035 | - |
dc.rights | cc-by (c) Efthymiou, Constantinos G. et al., 2019 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Cobalt | - |
dc.subject.classification | Magnetisme | - |
dc.subject.classification | Clústers metàl·lics | - |
dc.subject.classification | Metalls de terres rares | - |
dc.subject.other | Cobalt | - |
dc.subject.other | Magnetism | - |
dc.subject.other | Metal clusters | - |
dc.subject.other | Rare earth metals | - |
dc.title | A novel family of triangular CoII2LnIII and CoII2YIII clusters by the employment of Di-2-Pyridyl ketone | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 690646 | - |
dc.date.updated | 2019-07-16T07:55:54Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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690646.pdf | 1.22 MB | Adobe PDF | View/Open |
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