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Title: Access to indolines from primary phenylethylamines by an unexpected palladium- catalyzed C-H functionalization process
Author: Mancinelli, Andrea
Albert Mach, Joan
Ariza Piquer, Xavier
Barrios Moreno, Leoní Alejandra
García Gómez, Jordi
Gómez, Roberto
Granell Sanvicente, Jaime Ramón
Keywords: Pal·ladi (Element químic)
Issue Date: 29-Aug-2019
Publisher: Royal Society of Chemistry
Abstract: A new method for the preparation of 2,2-disubstituted indolines from 2-phenylethylamines was developed under Pd catalysis and PhI(OAc)2 as oxidant. Imines derived from 2-pyridinecarboxaldehyde were formed in situ to direct a C-H activation process. The resulting imines were also oxidized to the corresponding amides in the same Pd-catalyzed process to obtain the final indoline as a picolinamide.
Note: Reproducció del document publicat a:
It is part of: RSC Advances, 2019, vol. 9, num. 47, p. 27176-27182
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ISSN: 2046-2069
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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