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http://hdl.handle.net/2445/140436| Title: | Access to indolines from primary phenylethylamines by an unexpected palladium- catalyzed C-H functionalization process |
| Author: | Mancinelli, Andrea Albert Mach, Joan Ariza Piquer, Xavier Barrios Moreno, Leoní Alejandra García Gómez, Jordi Gómez, Roberto Granell Sanvicente, Jaime Ramón |
| Keywords: | Pal·ladi (Element químic) Catàlisi Palladium Catalysis |
| Issue Date: | 29-Aug-2019 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | A new method for the preparation of 2,2-disubstituted indolines from 2-phenylethylamines was developed under Pd catalysis and PhI(OAc)2 as oxidant. Imines derived from 2-pyridinecarboxaldehyde were formed in situ to direct a C-H activation process. The resulting imines were also oxidized to the corresponding amides in the same Pd-catalyzed process to obtain the final indoline as a picolinamide. |
| Note: | Reproducció del document publicat a: https://doi.org/10.1039/C9RA05670J |
| It is part of: | RSC Advances, 2019, vol. 9, num. 47, p. 27176-27182 |
| URI: | http://hdl.handle.net/2445/140436 |
| Related resource: | https://doi.org/10.1039/C9RA05670J |
| ISSN: | 2046-2069 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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| 691245.pdf | 540.64 kB | Adobe PDF | View/Open |
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