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http://hdl.handle.net/2445/142017
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DC Field | Value | Language |
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dc.contributor.author | Lazo-Jiménez, Rosa E. | - |
dc.contributor.author | Ortega-Alfaro, M. Carmen | - |
dc.contributor.author | López-Cortés, José G. | - |
dc.contributor.author | Alvarez-Toledano, Cecilio | - |
dc.contributor.author | Chávez-Carvayar, José A. | - |
dc.contributor.author | Ignés i Mullol, Jordi | - |
dc.contributor.author | González-Torres, Maykel | - |
dc.contributor.author | Carreón-Castro, Pilar | - |
dc.date.accessioned | 2019-10-10T07:21:15Z | - |
dc.date.available | 2019-10-10T07:21:15Z | - |
dc.date.issued | 2016-03-04 | - |
dc.identifier.issn | 1996-1944 | - |
dc.identifier.uri | http://hdl.handle.net/2445/142017 | - |
dc.description.abstract | The synthesis of four amphiphilic organometallic complexes with the general formula RC = M(CO)5NH(CH2)15CH3, where R is a ferrocenyl 2(a-b) or a phenyl 4(a-b) group as a donor moiety and a Fischer carbene of chromium (0) or tungsten (0) as an acceptor group, are reported. These four push-pull systems formed Langmuir (L) monolayers at the air-water interface, which were characterized by isotherms of surface pressure versus molecular area and compression/expansion cycles (hysteresis curves); Brewster angle microscopic images were also obtained. By using the Langmuir-Blodgett (LB) method, molecular monolayers were transferred onto glass substrates forming Z-type multilayers. LB films were characterized through ultraviolet-visible spectroscopy, atomic force microscopy and X-ray diffraction techniques. Results indicated that films obtained from 2b complex [(Ferrocenyl)(hexadecylamine)methylidene] pentacarbonyl tungsten (0) are the most stable and homogeneous; due to their properties, these materials may be incorporated into organic electronic devices. | - |
dc.format.extent | 1 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/ma9030167 | - |
dc.relation.ispartof | Materials, 2016, vol. 9, num. 3, p. 167-1-167-15 | - |
dc.relation.uri | https://doi.org/10.3390/ma9030167 | - |
dc.rights | cc-by (c) Lazo-Jiménez, Rosa E. et al., 2016 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Ciència dels Materials i Química Física) | - |
dc.subject.classification | Pel·lícules fines | - |
dc.subject.classification | Nanoestructures | - |
dc.subject.classification | Compostos carbonílics | - |
dc.subject.other | Thin films | - |
dc.subject.other | Nanostructures | - |
dc.subject.other | Carbonyl compounds | - |
dc.title | Nanostructured thin films obtained from Fischer aminocarbene complexes | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 659799 | - |
dc.date.updated | 2019-10-10T07:21:15Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 28773289 | - |
Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
Files in This Item:
File | Description | Size | Format | |
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659799.pdf | 2.04 MB | Adobe PDF | View/Open |
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