Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/142544| Title: | Coordination [CoII2] and [CoIIZnII] helicates showing slow magnetic relaxation |
| Author: | Diego, Rosa Pavlov, Alexander Darawsheh, Mohanad D. Aleshin, Dmitry Nehrkorn, Joscha Nelyubina, Yulia Roubeau, Olivier Novikov, Valentin Aromí Bedmar, Guillem |
| Keywords: | Molècules Propietats magnètiques Molecules Magnetic properties |
| Issue Date: | 8-Jul-2019 |
| Publisher: | American Chemical Society |
| Abstract: | The slow magnetic relaxation of CoII ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3]4+ and [CoZnL3]4+ coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic 1H NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.9b01334 |
| It is part of: | Inorganic Chemistry, 2019, vol. 58, num. 15, p. 9562-9566 |
| URI: | http://hdl.handle.net/2445/142544 |
| Related resource: | https://doi.org/10.1021/acs.inorgchem.9b01334 |
| ISSN: | 0020-1669 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 692135.pdf | 384.12 kB | Adobe PDF | View/Open |
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