Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/142718
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DC Field | Value | Language |
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dc.contributor.author | Mondal, Amit Kumar | - |
dc.contributor.author | Jover Modrego, Jesús | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.contributor.author | Konar, Sanjit | - |
dc.date.accessioned | 2019-10-22T07:12:39Z | - |
dc.date.available | 2019-10-22T07:12:39Z | - |
dc.date.issued | 2017-05-11 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/2445/142718 | - |
dc.description.abstract | In this work we report two pentacoordinated Co-II-P4X1 Single Ion Magnets (SIMs) based on P-donor ligands. The tetradentate ligand tris[2-(diphenylphosphino) ethyl] phosphine allows the obtention of the isostructural square pyramidal [Co(PP3)Cl]center dot ClO4 (1) and [Co(PP3)Br]center dot ClO4 (2) complexes. Consistent theoretical and experimental studies indicate that these complexes have a high spin (S = 3/2) ground state and suggest that the relaxation dynamics is governed by ground state quantum tunneling, whereas its temperature dependence is directed by optical or acoustic Raman processes. | - |
dc.format.extent | 4 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c7cc02584j | - |
dc.relation.ispartof | Chemical Communications, 2017, vol. 53, num. 38, p. 5338-5341 | - |
dc.relation.uri | https://doi.org/10.1039/c7cc02584j | - |
dc.rights | (c) Mondal, Amit Kumar et al., 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Imants | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Complexos metàl·lics | - |
dc.subject.other | Magnets | - |
dc.subject.other | Ligands | - |
dc.subject.other | Metal complexes | - |
dc.title | Investigation of easy-plane magnetic anisotropy in P-ligand square-pyramidal Co-II single ion magnets | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 673707 | - |
dc.date.updated | 2019-10-22T07:12:40Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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673707.pdf | 1.9 MB | Adobe PDF | View/Open |
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