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http://hdl.handle.net/2445/142918
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DC Field | Value | Language |
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dc.contributor.author | Wang, Long-Fei | - |
dc.contributor.author | Qiu, Jiang-Zhen | - |
dc.contributor.author | Hong, Jun-Yu | - |
dc.contributor.author | Chen, Yan-Cong | - |
dc.contributor.author | Li, Quan-Wen | - |
dc.contributor.author | Jia, Jian-Hua | - |
dc.contributor.author | Jover Modrego, Jesús | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.contributor.author | Liu, Jun-Liang | - |
dc.contributor.author | Tong, Ming-Liang | - |
dc.date.accessioned | 2019-10-23T14:15:54Z | - |
dc.date.available | 2019-10-23T14:15:54Z | - |
dc.date.issued | 2017-08-07 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/2445/142918 | - |
dc.description.abstract | The dimeric molecule [Dy-2(acac)(6)(MeOH)(2)(bpe)]center dot bpe center dot 2MeOH (1, acac = acetyl-acetonate, bpe = 1,2-bis(4-pyridyl)ethylene) undergoes a solidstate ligand substitution reaction upon heating, leading to the one-dimensional chain [Dy(acac)(3)(bpe)(n) (2). This structural transformation takes advantage of the potential coordination of the guest bpe molecules present in 1. In both complexes the Dy(III) ions adopt similar octatoordinated D-4d geometries, However, the different arrangement of the negatively charged and neutral ligands alters the direction of magnetic anisotropy axis and the energy states, thus resulting in largely distinct magnetization dynamics, as revealed by the CASSCF/RASSI calculations. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b00701 | - |
dc.relation.ispartof | Inorganic Chemistry, 2017, vol. 56, num. 15, p. 8829-8836 | - |
dc.relation.uri | https://doi.org/10.1021/acs.inorgchem.7b00701 | - |
dc.rights | (c) American Chemical Society , 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands (Bioquímica) | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.other | Ligands (Biochemistry) | - |
dc.subject.other | Magnetic properties | - |
dc.title | Tunable Magnetization Dynamics through Solid-State Ligand Substitution Reaction | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 673807 | - |
dc.date.updated | 2019-10-23T14:15:54Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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673807.pdf | 2.07 MB | Adobe PDF | View/Open |
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