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http://hdl.handle.net/2445/143162
Title: | Single-ion magnetic anisotropy in a vacant octahedral Co(II) complex |
Author: | Mondal, Amit Kumar Jover Modrego, Jesús Ruiz Sabín, Eliseo Konar, Sanjit |
Keywords: | Imants Anisotropia Relaxació magnètica Lligands Magnets Anisotropy Magnetic relaxation Ligands |
Issue Date: | 23-Oct-2018 |
Publisher: | Royal Society of Chemistry |
Abstract: | The first example of a pentacoordinate CoII single-ion magnet based on a P-donor ligand with vacant octahedral coordination geometry is reported here. Thorough magnetic measurements reveal the presence of field induced slow relaxation behavior with an easy-plane magnetic anisotropy. The combined theoretical and experimental studies disclose that direct and quantum tunneling processes become dominant at low temperature to relax the magnetization; however, from the thermal dependence of relaxation time it can be observed that the optical or acoustic Raman processes become important to the overall relaxation process. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1039/C8DT03862G |
It is part of: | Dalton Transactions, 2018, vol. 48, p. 25-29 |
URI: | http://hdl.handle.net/2445/143162 |
Related resource: | https://doi.org/10.1039/C8DT03862G |
ISSN: | 1477-9226 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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685747.pdf | 2 MB | Adobe PDF | View/Open |
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