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Title: Single-ion magnetic anisotropy in a vacant octahedral Co(II) complex
Author: Mondal, Amit Kumar
Jover Modrego, Jesús
Ruiz Sabín, Eliseo
Konar, Sanjit
Keywords: Imants
Relaxació magnètica
Magnetic relaxation
Issue Date: 23-Oct-2018
Publisher: Royal Society of Chemistry
Abstract: The first example of a pentacoordinate CoII single-ion magnet based on a P-donor ligand with vacant octahedral coordination geometry is reported here. Thorough magnetic measurements reveal the presence of field induced slow relaxation behavior with an easy-plane magnetic anisotropy. The combined theoretical and experimental studies disclose that direct and quantum tunneling processes become dominant at low temperature to relax the magnetization; however, from the thermal dependence of relaxation time it can be observed that the optical or acoustic Raman processes become important to the overall relaxation process.
Note: Versió postprint del document publicat a:
It is part of: Dalton Transactions, 2018, vol. 48, p. 25-29
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ISSN: 1477-9226
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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