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http://hdl.handle.net/2445/143377
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DC Field | Value | Language |
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dc.contributor.author | Cabré Montesinos, Albert | - |
dc.contributor.author | Cabezas Giménez, Juan José | - |
dc.contributor.author | Sciortino, Giuseppe | - |
dc.contributor.author | Ujaque, Gregori | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.contributor.author | Lledós, Agustí (Lledós i Falcó) | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.date.accessioned | 2019-10-28T17:19:34Z | - |
dc.date.available | 2020-07-01T05:10:26Z | - |
dc.date.issued | 2019-07-01 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | http://hdl.handle.net/2445/143377 | - |
dc.description.abstract | In the presence of 3-5 mol% Crabtree's catalyst or the corresponding tetrakis[3,5-bis(trifluoromethyl)phenyl]borate salt (Cy3P)Ir+(pyridine)(1,5-cyclooctadiene)·X- {X = PF6, [3,5-(F3C)2C6H3]4B}, aryl 1,1-disubstituted epoxides such as α-methylstyrene oxide underwent chemoselective isomerization to aldehydes; treatment with benzhydrylamine and pyrrolidine and redn. with NaBH4 yielded 2,2-disubstituted amines such as PhCHMeCH2NHR [R = Ph2CH, 4-MeOC6H4, PhCH2, (R)-PhCHMe] in one pot. DFT calcns. were performed to rationalize the obsd. selectivity. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/adsc.201900372 | - |
dc.relation.ispartof | Advanced Synthesis & Catalysis, 2019, vol. 361, num. 15, p. 3624-3631 | - |
dc.relation.uri | https://doi.org/10.1002/adsc.201900372 | - |
dc.rights | (c) Wiley-VCH, 2019 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Iridi | - |
dc.subject.classification | Isomerització | - |
dc.subject.other | Iridium | - |
dc.subject.other | Isomerization | - |
dc.title | Mild Iridium-Catalysed Isomerization of Epoxides. Computational Insights and Application to the Synthesis of β-Alkyl Amines | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 692336 | - |
dc.date.updated | 2019-10-28T17:19:35Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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692336.pdf | 580.92 kB | Adobe PDF | View/Open |
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