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http://hdl.handle.net/2445/149376
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DC Field | Value | Language |
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dc.contributor.author | Gómez Palomino, Alejandro | - |
dc.contributor.author | Pérez-Palau, Marina | - |
dc.contributor.author | Romea, Pedro | - |
dc.contributor.author | Urpí Tubella, Fèlix | - |
dc.contributor.author | Del Olmo, Marc | - |
dc.contributor.author | Hesse, Timo | - |
dc.contributor.author | Fleckenstein, Sonja | - |
dc.contributor.author | Gómez-Bengoa, Enrique | - |
dc.contributor.author | Sotorríos, Lía | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2020-02-04T13:32:42Z | - |
dc.date.available | 2021-01-03T06:10:18Z | - |
dc.date.issued | 2020-01-03 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/2445/149376 | - |
dc.description.abstract | Simple treatment of chiral titanium(IV) enolates with diacyl peroxides produces highly diastereoselective decarboxylative alkylations to efficiently deliver the corresponding adducts, most of which are not accessible through any of the current alkylating procedures. Such an unprecedented alkylation proceeds through an SET process that triggers the decomposition of the peroxide into a carbon-centered radical that finally combines with the resulting Cα radical. The procedure has been applied to the enantioselective synthesis of arundic acid. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.9b04148 | - |
dc.relation.ispartof | Organic Letters, 2020, vol. 22, num. 1, p. 199-203 | - |
dc.relation.uri | https://doi.org/10.1021/acs.orglett.9b04148 | - |
dc.rights | (c) American Chemical Society , 2020 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Estereoquímica | - |
dc.subject.classification | Titani | - |
dc.subject.other | Stereochemistry | - |
dc.subject.other | Titanium | - |
dc.title | Stereoselective decarboxylative alkylation of titanium(IV) enolates with diacyl peroxides | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 695056 | - |
dc.date.updated | 2020-02-04T13:32:43Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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695056.pdf | 492.32 kB | Adobe PDF | View/Open |
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