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http://hdl.handle.net/2445/152116
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DC Field | Value | Language |
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dc.contributor.author | Ramos Tomillero, Iván | - |
dc.contributor.author | Paradís Bas, Marta | - |
dc.contributor.author | Moreira, Ibério de Pinho Ribeiro | - |
dc.contributor.author | Bofill i Villà, Josep M. | - |
dc.contributor.author | Nicolás Galindo, Ernesto | - |
dc.contributor.author | Albericio Palomera, Fernando | - |
dc.date.accessioned | 2020-03-05T17:38:02Z | - |
dc.date.available | 2020-03-05T17:38:02Z | - |
dc.date.issued | 2015-03-26 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2445/152116 | - |
dc.description.abstract | The conventional electrophilic intramolecular aromatic substitution pathway proposed by Cresp et al. [J. Chem. Soc., Perkin Trans. 1 1973, 340 345] is confirmed by the observed products of phenolic formylation mediated by TiCl4. However, when the nucleophilic path is quenched by appropriate ligand modification, the initial equilibria between the possible neutral complexes of TiCl4 with 3,5-dimethoxy-phenol and/or diethyl ether lead to different stable diradical intermediates induced by valence tautomerism that provide valuable activated reagents. Some of these species have been detected by EPR, characterized theoretically and captured by TEMPO, thus providing a consistent mechanism for the reaction with one or more equivalents of TEMPO per phenol. | - |
dc.format.extent | 14 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/molecules20045409 | - |
dc.relation.ispartof | Molecules, 2015, vol. 20, num. 4, p. 5409-5422 | - |
dc.relation.uri | https://doi.org/10.3390/molecules20045409 | - |
dc.rights | cc-by (c) Ramos Tomillero, Iván et al., 2015 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Aldehids | - |
dc.subject.classification | Hidrocarburs aromàtics policíclics | - |
dc.subject.classification | Clorurs | - |
dc.subject.other | Aldehydes | - |
dc.subject.other | Polycyclic aromatic hydrocarbons | - |
dc.subject.other | Chlorides | - |
dc.title | Formylation of electron-rich aromatic rings mediated by dichloromethyl methyl ether and TiCl4: scope and limitations | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 649693 | - |
dc.date.updated | 2020-03-05T17:38:03Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 25822080 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Ciència dels Materials i Química Física) |
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649693.pdf | 843.67 kB | Adobe PDF | View/Open |
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