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http://hdl.handle.net/2445/152524
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DC Field | Value | Language |
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dc.contributor.author | Bartocci, Silvia | - |
dc.contributor.author | Sabaté, Ferran | - |
dc.contributor.author | Bosque Pueyo, Ramón | - |
dc.contributor.author | Keymeulen, Flore | - |
dc.contributor.author | Bartik, Kristin | - |
dc.contributor.author | Rodríguez Raurell, Laura | - |
dc.contributor.author | Dalla Cort, Antonella | - |
dc.date.accessioned | 2020-03-11T12:40:07Z | - |
dc.date.available | 2020-03-11T12:40:07Z | - |
dc.date.issued | 2016-12-01 | - |
dc.identifier.issn | 0143-7208 | - |
dc.identifier.uri | http://hdl.handle.net/2445/152524 | - |
dc.description.abstract | The synthesis and characterization of two new uranyl-salen complexes, 1-2, based on a 1,2-diaminomaleonitrile unit, is described. Spectroscopic studies to evaluate their potential as colorimetric probes for fluoride detection in chloroform and dichloromethane were undertaken. Compound 2 exhibits a 'turn-on' response characterized by a naked-eye colorimetric change for the selective recognition of fluoride in both solvents. DFT calculations show that the stabilization energy for the formation of the host:guest complex follows the trend F- > Cl- > Br- hence supporting the experimental data. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.dyepig.2016.06.006 | - |
dc.relation.ispartof | Dyes and Pigments, 2016, vol. 135, p. 94-101 | - |
dc.relation.uri | https://doi.org/10.1016/j.dyepig.2016.06.006 | - |
dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2016 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Urani | - |
dc.subject.classification | Teoria del funcional de densitat | - |
dc.subject.classification | Colorimetria | - |
dc.subject.other | Uranium | - |
dc.subject.other | Density functionals | - |
dc.subject.other | Colorimetry | - |
dc.title | Colorimetric and fluorescence 'turn-on' recognition of fluoride by a maleonitrile-based uranyl salen-complex | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 666200 | - |
dc.date.updated | 2020-03-11T12:40:07Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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666200.pdf | 1.49 MB | Adobe PDF | View/Open |
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