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http://hdl.handle.net/2445/152534
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DC Field | Value | Language |
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dc.contributor.author | Camps García, Pelayo | - |
dc.contributor.author | Gómez Nadal, Tània | - |
dc.contributor.author | Lozano Mena, David | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2020-03-11T17:00:51Z | - |
dc.date.available | 2020-03-11T17:00:51Z | - |
dc.date.issued | 2012-07-25 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2445/152534 | - |
dc.description.abstract | Reaction of 1,3-diphenylisobenzofuran (DPIBF) with 2-(iodoethynyl)(phenyl)- iodonium triflate at room temperature gave the expected Diels-Alder adduct, but using an excess of DFIBF (2 equiv.) and performing the reaction at 55 °C or heating at this temperature during the concentration stage, the initial orange solution or product mixture became dark brown and the products 1,2-phenylene-1,2-bis(phenylmethanone) and 2-(3-iodo-1,4-diphenylnaphthyl)(phenyl)iodonium triflate were obtained, which suggests an oxygen transfer between DPIBF and the initial adduct. | - |
dc.format.extent | 9 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/molecules17088795 | - |
dc.relation.ispartof | Molecules, 2012, vol. 17, num. 8, p. 8795-8803 | - |
dc.relation.uri | https://doi.org/10.3390/molecules17088795 | - |
dc.rights | cc-by (c) Camps García, Pelayo et al., 2012 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Espectroscòpia de ressonància magnètica nuclear | - |
dc.subject.classification | Difracció de raigs X | - |
dc.subject.other | Nuclear magnetic resonance spectroscopy | - |
dc.subject.other | X-rays diffraction | - |
dc.title | On the Reaction of 1,3-Diphenylisobenzofuran and (2-Iodoethynyl)(phenyl)iodonium Triflate. A Unique Case of Oxygen Transfer from the Diels-Alder Adduct to the Diene | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 615591 | - |
dc.date.updated | 2020-03-11T17:00:52Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 22832881 | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
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615591.pdf | 379.82 kB | Adobe PDF | View/Open |
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