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Title: | Synthesis of 2-(4,6-dimethyoxy-1,3,5-triazin-2-yloxyimino) Derivatives: Application in Solution Peptide Synthesis |
Author: | Al-Warhi, Tarfah I. AL-Hazimi, Hassan M.A. El-Faham, Ayman Albericio Palomera, Fernando |
Keywords: | Síntesi de pèptids Àcids carboxílics Triazoles Minerals d'urani Peptide synthesis Carboxylic acids Triazoles Uranium ores |
Issue Date: | 20-Dec-2010 |
Publisher: | MDPI |
Abstract: | A new class of 1,3,5-triazinyloxyimino derivatives were prepared, characterized and tested for reactivity in solution peptide synthesis. The new triazinyloxyimino derivatives failed to activate the carboxyl group during formation of peptide bonds, but gave the corresponding N-triazinyl amino acid derivatives as a major product. The oxyma (ethyl 2-cyano-2-(hydroxyimino)acetate) uronium salt was superior to other uronium salts in terms of racemization, while 2-chloro-4,6-dimethoxy-1,3,5-triazine (CDMT, 9) gave the best results. |
Note: | Reproducció del document publicat a: https://doi.org/10.3390/molecules15129403 |
It is part of: | Molecules, 2010, vol. 15, num. 12, p. 9403-9417 |
URI: | http://hdl.handle.net/2445/152616 |
Related resource: | https://doi.org/10.3390/molecules15129403 |
ISSN: | 1420-3049 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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