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http://hdl.handle.net/2445/152750
Title: | Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes |
Author: | Svahn, Noora Sanz Beguer, Ingrid Rissanen, Kari Rodríguez Raurell, Laura |
Keywords: | Or Compostos d'or Gold Gold compounds |
Issue Date: | 1-Oct-2019 |
Publisher: | Elsevier B.V. |
Abstract: | The synthesis of two dinuclear ionic complexes with chemical formula [Au(PR3)2][Au(C≡CC5H4N)2] that contain the water soluble phosphines, PR3, PTA (1, 3,5-triaza-7-phosphaadamantane, 1) and DAPTA (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 2) is herein described. The differences on their intermolecular reorganization have been analyzed and compared with the previously reported for the neutral complexes [Au(PR3)(C≡CC5H4N)]. It has been evidenced that the reorganization of the ligands giving rise to the dinuclear ionic complexes produces a complete change in the properties giving rise to Au***Au intermolecular assemblies. These aurophilic contacts are the responsible for the resulting luminescence which is not displayed for the parent compounds [Au(PR3)2]Cl and [PPh4][Au(C≡CC5H4N)2]. Compounds 1 and 2 were made react with three different silver salts (nitrate, triflate and hexafluorophosphate) giving rise to 1:1 heterometallic assemblies with some changes both on the wavelength and emission intensity. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.jorganchem.2019.07.001 |
It is part of: | Journal of Organometallic Chemistry, 2019, vol. 897, p. 170-177 |
URI: | http://hdl.handle.net/2445/152750 |
Related resource: | https://doi.org/10.1016/j.jorganchem.2019.07.001 |
ISSN: | 0022-328X |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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