Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/152812| Title: | Electrosynthesis of hydrogen peroxide in a filter-press flow cell using graphite felt as air-diffusion cathode |
| Author: | Pérez, Tzayam Coria, Gabriela Sirés Sadornil, Ignacio Nava, José L. Uribe, Agustín R. |
| Keywords: | Grafit Graphite |
| Issue Date: | 31-Jan-2018 |
| Publisher: | Elsevier B.V. |
| Abstract: | The electrosynthesis of H2O2 via O2 reduction was feasible employing cheap, unmodified graphite felt on top of carbon cloth as air-diffusion cathode fitted into an undivided filter-press cell. The experiments were performed in a pre-pilot plant with recirculation of 4 dm3 of 0.05 M Na2SO4 solutions at pH 3.0 upon continuous air feeding to the cathode. The H2O2 electrogeneration occurred within the range -0.30 < E < -0.01 V|SHE, being dependent on the mean linear flow velocity (u), which is related to the mass transport of hydronium ions. Optimum conditions achieved at E = -0.30 V|SHE and u = 27.4 cm s-1 yielded 100.4 mg dm-3 H2O2, with efficiency close to 100% and low energy consumption. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.jelechem.2018.01.054 |
| It is part of: | Journal of Electroanalytical Chemistry, 2018, vol. 812, p. 54-58 |
| URI: | http://hdl.handle.net/2445/152812 |
| Related resource: | https://doi.org/10.1016/j.jelechem.2018.01.054 |
| ISSN: | 1572-6657 |
| Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 676366.pdf | 2.28 MB | Adobe PDF | View/Open |
This item is licensed under a
Creative Commons License
