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http://hdl.handle.net/2445/153817| Title: | Designed intramolecular blocking of the spin crossover of an Fe(II) complex |
| Author: | Bartual-Murgui, C Vela, Sergio Roubeau, Olivier Aromí Bedmar, Guillem |
| Keywords: | Ferro Lligands Química supramolecular Iron Ligands Supramolecular chemistry |
| Issue Date: | 18-Aug-2016 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | A ligand derived from 1,3bpp (2-(pyrazol-1-yl)-6-(pyrazol-3-yl)-pyridine) has been prepared to prove that the spin crossover (SCO) of an Fe(II) complex can be blocked by means of intramolecular interactions not related to the crystal field. Calculations show that the blocking is caused by the energy penalty incurred by the rotation of a phenyl ring, needed to avoid steric hindrance upon SCO. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c6dt03047e |
| It is part of: | Dalton Transactions, 2016, vol. 45, num. 36, p. 14058-14062 |
| URI: | http://hdl.handle.net/2445/153817 |
| Related resource: | https://doi.org/10.1039/c6dt03047e |
| ISSN: | 1477-9226 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 667418.pdf | 681.37 kB | Adobe PDF | View/Open |
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