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Title: Designed intramolecular blocking of the spin crossover of an Fe(II) complex
Author: Bartual-Murgui, C
Vela, Sergio
Roubeau, Olivier
Aromí Bedmar, Guillem
Keywords: Ferro
Química supramolecular
Supramolecular chemistry
Issue Date: 18-Aug-2016
Publisher: Royal Society of Chemistry
Abstract: A ligand derived from 1,3bpp (2-(pyrazol-1-yl)-6-(pyrazol-3-yl)-pyridine) has been prepared to prove that the spin crossover (SCO) of an Fe(II) complex can be blocked by means of intramolecular interactions not related to the crystal field. Calculations show that the blocking is caused by the energy penalty incurred by the rotation of a phenyl ring, needed to avoid steric hindrance upon SCO.
Note: Versió postprint del document publicat a:
It is part of: Dalton Transactions, 2016, vol. 45, num. 36, p. 14058-14062
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ISSN: 1477-9226
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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