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Title: Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br- or I-)
Author: DDarawsheh, Mohanad D.
Barrios Moreno, Leoní Alejandra
Roubeau, Olivier
Teat, Simon J.
Aromí Bedmar, Guillem
Keywords: Ferro
Química supramolecular
Supramolecular chemistry
Issue Date: 5-Dec-2016
Publisher: Royal Society of Chemistry
Abstract: Ligand 1,3-bis(3-(pyridin-2-yl)-1H-pyrazol-5-yl) benzene, L, forms mononuclear spin crossover complexes [FeL3](2+) with pendant arms that cause them to dimerize through numerous intermolecular interactions forming supramolecular (X@[FeL3](3+) cations. They have the flexibility to encapsulate Cl-, Br- or I-), which allow tuning the magnetic properties, in the solid state and in solution.
Note: Versió postprint del document publicat a:
It is part of: Chemical Communications, 2016, vol. 53, num. 3, p. 569-572
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ISSN: 1359-7345
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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