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http://hdl.handle.net/2445/154124Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kishore, Pilli V.V. | - |
| dc.contributor.author | Rasamsetty, Amaleswari | - |
| dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
| dc.contributor.author | Baskar, Viswanathan | - |
| dc.date.accessioned | 2020-03-27T07:05:45Z | - |
| dc.date.available | 2020-03-27T07:05:45Z | - |
| dc.date.issued | 2015-12-23 | - |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | http://hdl.handle.net/2445/154124 | - |
| dc.description.abstract | Ferrocenyl betadiketones were reacted with hydrated lanthanide trihalides in presence of a base to yield red color solids, whose structures were characterized by single crystal X-ray diffraction technique. Structural analysis revealed the formation of nona- and tetranuclear lanthanide oxo-hydroxo clusters [Dy9(μ4-O)2(μ3-OH)8(μ-Fca)8(Fca)8]−[HN(C2H5)3]+ (1), [Ln4(μ-OH)2(μ-OCH3)4(CH3OH)2(Fctfa)6] Ln = Yb (2), Lu (3), and [Ln4(μ-OH)2(μ-OCH3)4(CH3OH)2(Fcpfa)6] Ln = Yb (4), Lu (5). Magnetism studies revealed that 1 shows slow relaxation of magnetisation. Cyclic voltammetry studies of 1 reveal electrochemically stable quasi reversible oxidation systems whereas 2-5 showed irreversible nature. | - |
| dc.format.extent | 5 p. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Elsevier Ltd | - |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2015.10.017 | - |
| dc.relation.ispartof | Polyhedron, 2015, vol. 102, p. 361-365 | - |
| dc.relation.uri | https://doi.org/10.1016/j.poly.2015.10.017 | - |
| dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2015 | - |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
| dc.subject.classification | Terres rares | - |
| dc.subject.classification | Imants | - |
| dc.subject.classification | Difracció de raigs X | - |
| dc.subject.other | Rare earths | - |
| dc.subject.other | Magnets | - |
| dc.subject.other | X-rays diffraction | - |
| dc.title | Redox shield enfolding a magnetic core | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/acceptedVersion | - |
| dc.identifier.idgrec | 662178 | - |
| dc.date.updated | 2020-03-27T07:05:46Z | - |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 662178.pdf | 650.01 kB | Adobe PDF | View/Open |
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