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http://hdl.handle.net/2445/154179
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DC Field | Value | Language |
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dc.contributor.author | Agarwal, Rashmi A. | - |
dc.contributor.author | Mukherjee, Soumya | - |
dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
dc.contributor.author | Ghosh, Sujit K | - |
dc.contributor.author | Bharadwaj, Parimal K | - |
dc.date.accessioned | 2020-03-27T07:28:27Z | - |
dc.date.available | 2020-03-27T07:28:27Z | - |
dc.date.issued | 2014-10-21 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | http://hdl.handle.net/2445/154179 | - |
dc.description.abstract | A porous coordination polymer {[Mn2(DBIBA)3]×(NO3)·3DMF·4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. This compound shows significant selective CO2 uptake at low temperature. 1 exhibits antiferromagnetic properties below 17 K, confirmed by magnetic susceptibility measurements. Four new coordination polymers: {[Mn2(DBIBA)3]·ClO4·3DMF·3H2O}n (2), {[Mn2(DBIBA)3]×Cl×DMF×H2O}n (3), {[Mn2(DBIBA)3]×NO3×CH3OH×7H2O}n (4) and {[Mn2(DBIBA)3]×NO3×2CH3COCH3×H2O}n (5), have been synthesized from 1 via anion/solvent exchange protocols at room temperature. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/cg500833s | - |
dc.relation.ispartof | Crystal Growth & Design, 2014, vol. 14, num. 11, p. 5585-5592 | - |
dc.relation.uri | https://doi.org/10.1021/cg500833s | - |
dc.rights | (c) American Chemical Society , 2014 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Química organometàl·lica | - |
dc.subject.other | Ligands | - |
dc.subject.other | Organometallic chemistry | - |
dc.title | Gas adsorption, magnetism, and single-crystal to single-crystal transformation studies of a three-dimensional Mn(II) porous coordination polymer | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 655077 | - |
dc.date.updated | 2020-03-27T07:28:27Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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655077.pdf | 6.17 MB | Adobe PDF | View/Open |
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