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http://hdl.handle.net/2445/154185| Title: | Designed asymmetric coordination helicates with bis-beta-diketonate ligands |
| Author: | Diego, Rosa Darawsheh, Mohanad D. Barrios Moreno, Leoní Alejandra Sadurní, Anna Garcia-Anton, Jordi Lloyd-Williams, Paul Teat, Simon J. Roubeau, Olivier Aguilà Avilés, David Aromí Bedmar, Guillem |
| Keywords: | Lligands Coure Difracció de raigs X Ligands Copper X-rays diffraction |
| Issue Date: | 23-Nov-2019 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | A new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(iii) and Ga(iii) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups. © 2019 The Royal Society of Chemistry. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/C9DT03398J |
| It is part of: | Dalton Transactions, 2019, vol. 48, num. 45, p. 16844-16847 |
| URI: | http://hdl.handle.net/2445/154185 |
| Related resource: | https://doi.org/10.1039/C9DT03398J |
| ISSN: | 1477-9226 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 693752.pdf | 652.1 kB | Adobe PDF | View/Open |
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