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http://hdl.handle.net/2445/154186| Title: | Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies |
| Author: | Velasco Amigó, Verónica Barrios Moreno, Leoní Alejandra Schütze, Mike Roubeau, Olivier Luis Vitalla, Fernando Teat, Simon J. Aguilà Avilés, David Aromí Bedmar, Guillem |
| Keywords: | Terres rares Imants Compostos de coordinació Rare earths Magnets Coordination compounds |
| Issue Date: | 10-Sep-2019 |
| Publisher: | Wiley-VCH |
| Abstract: | The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1002/chem.201903829 |
| It is part of: | Chemistry-A European Journal, 2019, vol. 25, num. 67, p. 15228-15232 |
| URI: | http://hdl.handle.net/2445/154186 |
| Related resource: | https://doi.org/10.1002/chem.201903829 |
| ISSN: | 0947-6539 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 693888.pdf | 364.74 kB | Adobe PDF | View/Open |
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