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http://hdl.handle.net/2445/154365
Title: | Three lanthanide complexes with mixed salicylate and 1,10-phenanthroline: syntheses, crystal structures, and luminescent/magnetic properties |
Author: | Hu, Min Yue, Ling-Yu Sañudo Zotes, Eva Carolina Fang, Shao-Ming |
Keywords: | Terres rares Imants Estructura cristal·lina (Sòlids) Luminescència Propietats magnètiques Rare earths Magnets Layer structure (Solids) Luminescence Magnetic properties |
Issue Date: | 1-Jan-2016 |
Publisher: | Taylor and Francis |
Abstract: | Three new lanthanide complexes incorporating salicylate (HSA or SA) and 1,10-phenanthroline (phen), Ln(3)(HSA)(5)(SA)(2)(phen)(3) [Ln=Ho (1) and Er (2)], and Sm-2(HSA)(2)(SA)(2)(phen)(3) (3), have been synthesized. X-ray structural analysis reveals that 1 and 2 are isostructural with a trinuclear pattern, and 3 exhibits a binuclear structure. Comparison of the structural differences between 1/2 and 3 suggests that the identity of metal plays an important role in construction of such complexes. The magnetic properties of 1 are discussed. Moreover, 2 and 3 are both photoluminescent materials, and their emission properties are closely related to their corresponding Ln(III) centers. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1080/00958972.2016.1198477 |
It is part of: | Journal of Coordination Chemistry, 2016, vol. 69, num. 14, p. 2164-2173 |
URI: | http://hdl.handle.net/2445/154365 |
Related resource: | https://doi.org/10.1080/00958972.2016.1198477 |
ISSN: | 0095-8972 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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