Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/154388
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dc.contributor.authorLedezma Gairaud, Marisol-
dc.contributor.authorPineda, L.W.-
dc.contributor.authorAromí Bedmar, Guillem-
dc.contributor.authorSañudo Zotes, Eva Carolina-
dc.date.accessioned2020-03-30T10:15:14Z-
dc.date.available2020-03-30T10:15:14Z-
dc.date.issued2015-06-09-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/2445/154388-
dc.description.abstractMicrowave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented.-
dc.format.extent6 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.ica.2015.05.030-
dc.relation.ispartofInorganica Chimica Acta, 2015, vol. 434, p. 215-220-
dc.relation.urihttps://doi.org/10.1016/j.ica.2015.05.030-
dc.rightscc-by (c) Mognon, Lorenzo et al.-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subject.classificationLligands-
dc.subject.classificationPropietats magnètiques-
dc.subject.otherLigands-
dc.subject.otherMagnetic properties-
dc.titleSynthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec653128-
dc.date.updated2020-03-30T10:15:14Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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