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http://hdl.handle.net/2445/154553| Title: | Increasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited state |
| Author: | Oyarzabal, I. Ruiz Dueñas, J. Ruiz Sabín, Eliseo Aravena Ponce, Daniel Alejandro Seco, J. M. Colacio, Enrique |
| Keywords: | Magnetisme Ions metàl·lics Magnetism Metal ions |
| Issue Date: | 17-Jun-2015 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | The trinuclear complex [ZnCl(l-L)Dy(l-L)ClZn]PF6 exhibits a single- molecule magnetic behaviour under zero field with a relatively large effective energy barrier of 186 cm1. Ab initio calculations reveal that the relaxation of the magnetization is symmetry-driven (the DyIII ion possesses a C2 symmetry) and occurs via the second excited state. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c5cc04495b |
| It is part of: | Chemical Communications, 2015, vol. 51, num. 62, p. 12353-12356 |
| URI: | http://hdl.handle.net/2445/154553 |
| Related resource: | https://doi.org/10.1039/c5cc04495b |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 656357.pdf | 2.18 MB | Adobe PDF | View/Open |
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