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http://hdl.handle.net/2445/154598
Title: | A trinuclear CuII complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment |
Author: | Maxwell Villacorta, Lindley Andrés Gómez-Coca, Silvia Weyhermüller, Thomas Panyella, David Ruiz Sabín, Eliseo |
Keywords: | Fotocatàlisi Química supramolecular Photocatalysis Supramolecular chemistry |
Issue Date: | 29-Jul-2015 |
Publisher: | Royal Society of Chemistry |
Abstract: | A new kind of N-ligands based on heptazine derivatives is presented. A trinuclear CuII complex, [(L)2CuII3Cl3](ClO4)3·3CH2Cl2 (L=2,5,8-tris-(di-2-pyrildylamine) heptazine), utilizing a pyridine derivative of heptazine has been synthesized and characterized avoiding the inherent solubility problems of heptazine compounds. Thus, this work opens the application of such ligands either in supramolecular chemistry as a larger ligand of the widely used s-triazine derivatives or to provide molecular systems for photocatalysis as heptazine is the fundamental unit of the very promising g-C3N4 2D compound. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c5dt02485d |
It is part of: | Dalton Transactions, 2015, vol. 44, num. 36, p. 15761-15763 |
URI: | http://hdl.handle.net/2445/154598 |
Related resource: | https://doi.org/10.1039/c5dt02485d |
ISSN: | 1477-9226 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
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656349.pdf | 340.9 kB | Adobe PDF | View/Open |
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