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Title: Negatively charged metallacarborane redox couples with both members stable to air
Author: Lupu, Marius
Zaulet, Adnana
Teixidor, Francesc
Ruiz Sabín, Eliseo
Viñas, Clara
Keywords: Cobalt
Reacció d'oxidació-reducció
Oxidation-reduction reaction
Issue Date: 27-Apr-2015
Publisher: Wiley-VCH
Abstract: It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air.
Note: Versió postprint del document publicat a:
It is part of: Chemistry-A European Journal, 2015, vol. 21, num. 18, p. 6888-6897
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ISSN: 0947-6539
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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