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http://hdl.handle.net/2445/159723| Title: | Negatively charged metallacarborane redox couples with both members stable to air |
| Author: | Lupu, Marius Zaulet, Adnana Teixidor, Francesc Ruiz Sabín, Eliseo Viñas, Clara |
| Keywords: | Cobalt Reacció d'oxidació-reducció Cobalt Oxidation-reduction reaction |
| Issue Date: | 27-Apr-2015 |
| Publisher: | Wiley-VCH |
| Abstract: | It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1002/chem.201406244 |
| It is part of: | Chemistry-A European Journal, 2015, vol. 21, num. 18, p. 6888-6897 |
| URI: | http://hdl.handle.net/2445/159723 |
| Related resource: | https://doi.org/10.1002/chem.201406244 |
| ISSN: | 0947-6539 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 653202.pdf | 947.29 kB | Adobe PDF | View/Open |
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