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Title: Iron hydride radical reductive alkylation of unactivated alkenes
Author: Saladrigas, Mar
Bonjoch i Sesé, Josep
Bradshaw, Ben
Keywords: Alquens
Issue Date: 30-Dec-2019
Publisher: American Chemical Society
Abstract: Iron-catalyzed hydrogen atom transfer-mediated intermolecular C−C coupling reactions between alkenes and tosylhydrazones, followed by in situ cleavage of the tosylhydrazine intermediates using Et3N, are described. The process involves a new strategic bond disconnection resulting in the reductive alkylation of nonactivated alkenes. The reaction is operationally simple, proceeds under mild conditions, and has a wide substrate scope.
Note: Versió postprint del document publicat a:
It is part of: Organic Letters, 2019, vol. 22, num. 2, p. 684-688
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ISSN: 1523-7060
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
Articles publicats en revistes (Institut de Biomedicina (IBUB))

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