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http://hdl.handle.net/2445/159757
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DC Field | Value | Language |
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dc.contributor.author | Xie, Ya-Bo | - |
dc.contributor.author | Gan, Lei | - |
dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
dc.contributor.author | Zheng, Haiyang | - |
dc.contributor.author | Zhao, Jiongpeng | - |
dc.contributor.author | Zhao, Minjian | - |
dc.contributor.author | Wang, Bin | - |
dc.contributor.author | Li, Jian-Rong | - |
dc.date.accessioned | 2020-05-12T08:59:09Z | - |
dc.date.available | 2020-05-12T08:59:09Z | - |
dc.date.issued | 2015-06-14 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | http://hdl.handle.net/2445/159757 | - |
dc.description.abstract | As the first example of using a parent tetrazole and an azide together in preparing magnetic complexes, two novel tetrazolate-azido-bridged Cu(ii) coordination polymers, [Cu(tz)(N3)]n (1) and [Cu(tz)(N3)(NH3)2]n (2) (tz = tetrazolate), have been synthesized through the reaction of Htz, CuCl2, and NaN3 under hydrothermal conditions and in ammonia solution at room temperature, respectively. Single crystal X-ray structure analysis reveals that the two complexes possess distinct three-dimensional (3D) framework structures and can be topologically described as a 3-connected srs (SrSi2)-type net and a 4-connected cds (CdSO4)-type net, respectively. Both tetrazolate and azide groups also have different linkage modes in the two complexes. 1 contains end-on (EO) type azide bridges and 3-connected tetrazolate, while 2 possess end-to-end (EE) azide linkers and 2-coordinated tetrazolate. Magnetic measurements indicate that antiferrimagnetic interactions dominate between Cu(ii) ions in the two complexes with the corresponding magnetic coupling constant being J = -41.0 cm-1 in 1 and J = -8.62 cm-1 in 2. | - |
dc.format.extent | 7 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c5ce00531k | - |
dc.relation.ispartof | Crystengcomm, 2015, vol. 17, num. 22, p. 4136-4142 | - |
dc.relation.uri | https://doi.org/10.1039/c5ce00531k | - |
dc.rights | (c) Xie, Ya-Bo et al., 2015 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.other | Ligands | - |
dc.subject.other | Layer structure (Solids) | - |
dc.subject.other | Magnetic properties | - |
dc.title | TetrazolateazidocopperIJII) coordination polymers: tuned synthesis, structure, and magnetic properties | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 655010 | - |
dc.date.updated | 2020-05-12T08:59:09Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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655010.pdf | 846.66 kB | Adobe PDF | View/Open |
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