Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/160142| Title: | Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate |
| Author: | Esquius, G. Pons, Josefina Yáñez, R. Ros, J. Solans, Xavier, 1949-2007 Font Bardia, Ma. Mercedes |
| Keywords: | Cristal·lografia Crystallography |
| Issue Date: | 2002 |
| Publisher: | International Union of Crystallography |
| Abstract: | In the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclooctadiene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing. |
| Note: | Reproducció del document publicat a: https://doi.org/10.1107/S0108270101020017 |
| It is part of: | Acta Crystallographica Section C: Crystal Structure Communications, 2002, num. 58, p. m133-m134 |
| URI: | http://hdl.handle.net/2445/160142 |
| Related resource: | https://doi.org/10.1107/S0108270101020017 |
| ISSN: | 0108-2701 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 563147.pdf | 94.58 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.