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http://hdl.handle.net/2445/160862
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DC Field | Value | Language |
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dc.contributor.author | Casanovas Bayo, Berta | - |
dc.contributor.author | Speed, Saskia | - |
dc.contributor.author | El Fallah El Boufrahi, Mohamed Salah | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Zinna, Francesco | - |
dc.contributor.author | Di Bari, Lorenzo | - |
dc.date.accessioned | 2020-05-18T08:56:58Z | - |
dc.date.available | 2020-05-18T08:56:58Z | - |
dc.date.issued | 2019-01-10 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/2445/160862 | - |
dc.description.abstract | The reaction of LnCl3·6H2O with (S)-(+)-2-(6-methoxy-2-naphthyl)propionic acid (S-HL), best known as naproxen, and 1,10-phenanthroline (phen) in EtOH allows the isolation of dinuclear chiral compounds S-1-4 of the formula [Ln2(S-L)6(phen)2]·3DMF·H2O [Ln(III) = Eu (1), Gd (2), Tb (3) and Dy (4)]. The use of the R-enantiomeric species of the HL ligand led to complexes R-1-4 with the formula [Ln2(R-L)6(phen)2]·3DMF·H2O. Compounds R- and S-1, 3 and 4 show strong sensitized metal-centred luminescence in the visible region. Moreover, Dy(III) complexes R- and S-4 display field-induced singlemolecule magnet (SMM) behaviour. For chiral and emissive compounds circularly polarized luminescence (CPL) measurements have also been performed. | - |
dc.format.extent | 27 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/C8DT04149K | - |
dc.relation.ispartof | Dalton Transactions, 2019, vol. 48, num. 6, p. 2059-2067 | - |
dc.relation.uri | https://doi.org/10.1039/C8DT04149K | - |
dc.rights | (c) Casanovas Bayo, Berta et al., 2019 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.classification | Magnetisme | - |
dc.subject.other | Layer structure (Solids) | - |
dc.subject.other | Magnetism | - |
dc.title | Chiral Dinuclear Ln(III) Complexes Derived from S- and R-2-(6-methoxy-2-naphthyl)propionate. Optical and Magnetic Properties. | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 684272 | - |
dc.date.updated | 2020-05-18T08:56:59Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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684272.pdf | 1.37 MB | Adobe PDF | View/Open |
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