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http://hdl.handle.net/2445/161578
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DC Field | Value | Language |
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dc.contributor.author | Soldevila-Sanmartín, Joan | - |
dc.contributor.author | Sánchez-Sala, M. | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Ayllón, J. A. | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2020-05-20T08:39:53Z | - |
dc.date.available | 2020-11-05T06:10:24Z | - |
dc.date.issued | 2018-11-05 | - |
dc.identifier.issn | 0022-2860 | - |
dc.identifier.uri | http://hdl.handle.net/2445/161578 | - |
dc.description.abstract | [Cu(μ-MeCO2)2(4-Bzpy)]2 (4-Bzpy = 4-benzylpyridine) has been synthesized by reaction of [Cu(μ-MeCO2)2(H2O)]2 with 4-Bzpy in methanol at room temperature. The compound was characterized by Elemental Analysis, ATR-FTIR and X-ray Powder Diffraction. The molecular structure was determined by single crystal X-ray diffraction analysis at 100 K and 303 K. The compound consists of binuclear units where both Cu(II) atoms are linked by four syn-syn carboxylate bridges, showing a paddle-wheel unit. The role of CH⋯O hydrogen bonds in the establishment of its supramolecular network is discussed, comparing the resulting structural parameters at the two different temperatures. Finally, the thermal variation of XpT for compound 1 has also been studied, suggesting an antiferromagnetic Cu⋯Cu interaction (J = −311 cm−1), which agrees with the presence of four μ-κO-κO′ carboxylates bridging the metallic centers in the binuclear complex. | - |
dc.format.extent | 24 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2018.06.056 | - |
dc.relation.ispartof | Journal of Molecular Structure, 2018, vol. 1171, p. 808-814 | - |
dc.relation.uri | https://doi.org/10.1016/j.molstruc.2018.06.056 | - |
dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2018 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Materials porosos | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.other | Porous materials | - |
dc.subject.other | Layer structure (Solids) | - |
dc.title | [Cu(mu-MeCO2)(2)(4-Bzpy)](2) (4-Bzpy=4-benzylpyridine): Study of the intermolecular C-H···O hydrogen bonds at two temperatures | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 685056 | - |
dc.date.updated | 2020-05-20T08:39:53Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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685056.pdf | 1.97 MB | Adobe PDF | View/Open |
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