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http://hdl.handle.net/2445/161979| Title: | {Ni4} Cubanes from enantiomerically pure 2-(1-hydroxyethyl)pyridine ligands: supramolecular chirality |
| Author: | Mayans Ayats, Júlia Athanasopoulou, Angeliki A. Pham, A.T. Font Bardia, Ma. Mercedes Mazarakioti, Eleni C. Pilkington, M. Stamatatos, T.C. Escuer Fité, Albert |
| Keywords: | Quiralitat Magnetisme Chirality Magnetism |
| Issue Date: | 1-Apr-2019 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | Homometallic {NiII4} cubane-like clusters with a rare chiral core have been prepared via the employment of enantiomerically pure 2-(1-hydroxyethyl)pyridine (Hmpm). Comparison with the achiral cubanes derived from the related 2-pyridinemethanol (Hpym) ligand reveals drastic structural changes as a consequence of the transfer of chirality from the ligands to the whole structure. Their magnetic properties have been related to the structural features of their cubane-type cores. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/C9DT01026B |
| It is part of: | Dalton Transactions, 2019, vol. 48, num. 28, p. 10427-10434 |
| URI: | http://hdl.handle.net/2445/161979 |
| Related resource: | https://doi.org/10.1039/C9DT01026B |
| ISSN: | 1477-9226 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 690645.pdf | 1.72 MB | Adobe PDF | View/Open |
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