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http://hdl.handle.net/2445/162075| Title: | Decanuclear FeIII clusters with hemiacetal ligands: a new{M10(μ3-O)8} cluster core |
| Author: | Mayans Ayats, Júlia Roc, L. Font Bardia, Ma. Mercedes Escuer Fité, Albert |
| Keywords: | Lligands (Bioquímica) Hidròlisi Compostos organometàl·lics Ligands (Biochemistry) Hydrolysis Organometallic compounds |
| Issue Date: | 1-Jul-2019 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | The characterization of a decanuclear FeIII cluster with α-methyl- 2-pyridinemethanolate, generated by the hydrolysis of Schiff bases, inspired us to carry out an initial exploration of the direct syntheses of medium nuclearity FeIII clusters starting from aldehydes in methanolic medium. The new complexes exhibit an unprecedented {Fe10(μ3-O)8} cluster core. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c9dt01568j |
| It is part of: | Journal of the Chemical Society, Dalton Transactions, 2019, vol. 48, num. 35, p. 13139-13142 |
| URI: | http://hdl.handle.net/2445/162075 |
| Related resource: | https://doi.org/10.1039/c9dt01568j |
| ISSN: | 1472-7773 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 691778.pdf | 994.51 kB | Adobe PDF | View/Open |
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