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http://hdl.handle.net/2445/162699| Title: | Triple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization |
| Author: | Mayans Ayats, Júlia Font Bardia, Ma. Mercedes Escuer Fité, Albert |
| Keywords: | Lligands Propietats magnètiques Halògens Cations Metalls de transició Ligands Magnetic properties Halogens Cations Transition metals |
| Issue Date: | 5-Feb-2018 |
| Publisher: | American Chemical Society |
| Abstract: | A family of decanuclear chiral clusters with a (Mn2Mn6Na2I)-Mn-II-Na-III core have been synthesized from enantiomerically pure Schiff bases. The new systems consist of two (Mn2Mn6Na2I)-Mn-II-Na-III units linked by rare triple chloro or bromo bridges between the divalent Mn cations. Susceptibility measurements point out the weak anti ferromagnetic interaction mediated by these kinds of bridges and afford the first magnetic measurements for the (mu-Br)(3) case. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b03125 |
| It is part of: | Inorganic Chemistry, 2018, vol. 57, num. 3, p. 926-929 |
| URI: | http://hdl.handle.net/2445/162699 |
| Related resource: | https://doi.org/10.1021/acs.inorgchem.7b03125 |
| ISSN: | 0020-1669 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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|---|---|---|---|---|
| 681397.pdf | 871.45 kB | Adobe PDF | View/Open |
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