Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/163392
Title: | Solvent-controlled formation of monomeric and dimeric species containing Cu(II) acetate and 4-phenylpyridine |
Author: | Soldevila-Sanmartín, Joan Ayllón, J. A. Calvet Pallàs, Maria Teresa Font Bardia, Ma. Mercedes Pons, Josefina |
Keywords: | Coure Estructura cristal·lina (Sòlids) Copper Layer structure (Solids) |
Issue Date: | 28-Jun-2017 |
Publisher: | Elsevier Ltd |
Abstract: | Three copper(II) acetate complexes with 4-phenylpyridine (4-Phpy), namely [Cu(MeCO2)2(4- Phpy)2(H2O)2] (1), [Cu(MeCO2)2(4-Phpy)2(H2O)1.5] (2) and [Cu(MeCO2)2(4-Phpy)]2 (3), were synthesized and characterized by analytical and spectroscopic methods. Experimental conditions as solvent or temperature determine the species obtained. Crystal and molecular structure of 2 was determined by Xray diffraction. Compound 2 presents a singular structure, containing two crystallographic independent mononuclear units [Cu(MeCO2)2(4-Phpy)2(H2O)2] (2A) and [Cu(MeCO2)2(4-Phpy)2(H2O)] (2B) in its unit cell and each of these forms an independent 1-D chain through H-bonding. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2017.06.049 |
It is part of: | Polyhedron, 2017, vol. 135, p. 36-40 |
URI: | http://hdl.handle.net/2445/163392 |
Related resource: | https://doi.org/10.1016/j.poly.2017.06.049 |
ISSN: | 0277-5387 |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
676858.pdf | 1.23 MB | Adobe PDF | View/Open |
This item is licensed under a Creative Commons License